(Z)-2-Amino-3-[(E)-benzylideneamino]but-2-enedinitrile

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(Z)-2-Amino-3-[(E)-benzyl­ideneamino]but-2-enedinitrile

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(E)-2,3-Bis[(E)-benzyl­idene­amino]­but-2-enedinitrile

The asymmetric unit of the title compound, C(18)H(12)N(4), consists of a half-mol-ecule, where the two halves of the mol-ecule are related by inversion symmetry. The mol-ecule is effectively planar, with the largest deviation from the 22-atom mean plane, measuring 0.024 (2) Å, exhibited by the ortho-C atom of the phenyl ring. The crystal structure exhibits π-stacking, with an inter-planar spaci...

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2-Amino-3-[(E)-(2-hy­droxy-3-methyl­benzyl­idene)amino]­but-2-ene­dinitrile

The title compound, C(12)H(10)N(4)O, is a Schiff base obtained from the condensation of diamino-maleonitrile and 2-hy-droxy-3-methyl-benzaldehyde. The mol-ecule is roughly planar, with an r.m.s. deviation of 0.0354 Å, and adopts the phenol-imine tautomeric form. An intra-molecular O-H⋯N hydrogen bond involving the O-H group and the azomethine N atom generates an S(6) ring. In the crystal, there...

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2-((Z)-{3-[(Z)-(2-Hy­droxy-5-methyl­benzyl­idene)amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4-methyl­phenol

In the title compound, C(21)H(26)N(2)O(2), the dihedral angle between the two benzene rings is 73.47 (16)°. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. The substituted benzene rings are twisted around the central quaternary C atom in opposite directions, making a vault geometry.

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2-[(Z)-(3-{[(Z)-2-Hy­droxy-3,5-diiodo­benzyl­idene]amino}­propyl­imino)­meth­yl]-4,6-diiodo­phenol

In the title compound, C(17)H(14)I(4)N(2)O(2), there are two intra-molecular O-H⋯N hydrogen bonds, which make S(6) ring motifs. In the crystal, there are no significant inter-molecular inter-actions present.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809010873